탄소나노튜브 첨가에 따른 PTFE 도료의 물성변화 연구
- Alternative Title
- The Effect of Carbonnanotube on Mechanical Properties of PTFE(Polytetrafluoroethylene)
- Abstract
- Carbon nanotubes(CNT) have been in the focus of scientific attention ever since their discovery in 1993. Most often visualized as rolled-up graphite sheets with diameters between 0.5 and 2 nm and lengths of several micrometers, these unique structures are expected to have a serious impact on nano industry soon.
Carbon nanotubes exhibit extraordinary mechanical and electronic properties. However, manipulation and processing of CNT has been limited by their insolubility in most common solvents, although some dissolution has recently been obtained. Wrapping with polymers has also provided a supramolecular approach to solubilization of CNT. Considerable effort has therefore been devoted to the chemical modification of CNT, which might pave the way to many useful applications, including composite preparations.
carbon nanotubes were oxidatively functionalized by sulfuric/nitric acid treatment. The presence of carboxyl groups and properties of CNT/PTFE composite applications was proven by IR spectroscopy, zeta Potential, Contact angle, TGA and so on. The implications of the surface modification are discussed primarily in terms of nanotube -polymer composite.
This studies show the improvement of mechanical, electronic properties of nanotube polymer composites by the surface modification of CNT.
- Author(s)
- 이현우
- Issued Date
- 2008
- Awarded Date
- 2008. 8
- Type
- Dissertation
- Keyword
- 탄소나노튜브 고분자 복합체 불소 도료
- Publisher
- 부경대학교 대학원
- URI
- https://repository.pknu.ac.kr:8443/handle/2021.oak/11189
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001955625
- Alternative Author(s)
- Lee, Hyeon-woo
- Affiliation
- 부경대학교 대학원
- Department
- 대학원 공업화학과
- Advisor
- 곽삼탁
- Table Of Contents
- 1. 서론 = 1
2. 이론적 배경 = 3
2-1. 탄소나노튜브 = 3
2-1-1. 탄소나노튜브의 개요 = 3
2-1-2. 탄소나노튜브의 합성법 = 6
2-1-3. 탄소나노튜브의 물리적 특성 = 8
2-1-3-1. 전기적 성질 = 8
2-1-3-2. 기계적 성질 = 8
2-1-3-3. 열적 성질 = 9
2-1-3-4. 물리적 성질 = 10
2-2. 불소 수지 = 11
2-2-1. 불소 고분자 = 11
2-2-2. PTFE = 13
2-2-3. 불소 수지 도료의 특성 = 16
2-3. 탄소나노튜브/고분자 복합체 = 17
3. 실 험 = 19
3-1. 시약 = 19
3-2. 시편 제조 = 19
3-2-1. 카르복실기를 도입한 탄소나노튜브 제조 = 19
3-2-2. 탄소나노튜브/고분자 복합체 제조 = 21
3-3. 분석 = 22
3-3-1. 카르복실기를 도입한 탄소나노튜브 분석 = 22
3-3-2. 탄소나노튜브/고분자 복합체 분석 = 23
4. 결과 = 24
4-1. 카르복실기를 도입한 탄소나노튜브 = 24
4-1-1. FT-IR 측정 = 24
4-1-2. TGA 측정 = 26
4-1-3. Zeta Potential 측정 = 28
4-2. 탄소나노튜브/PTFE 복합체 = 30
4-2-1. Pendulum Hardness Test = 30
4-2-2. Contact Angle Test = 32
4-2-3. TGA 측정 = 34
4-2-4. 전기전도도 측정 = 35
4-2-5. SEM 측정 = 37
5. 결론 = 39
참고문헌 = 40
- Degree
- Master
-
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- 대학원 > 공업화학과
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