Burn Damage 온도에 따른 Epoxy Paint의 방청성 평가
- Alternative Title
- The study on the corrosion resistance of epoxy paint with temperature variation burn damaged
- Abstract
- In making blocks for building offshore plants and ships, it has been generalized to do painting after finishing the outfitting work just before mounting. However, a correction part may take place during material input due to the delay of outfit materials, defect repairing, welding omission, etc.
As a result, after painting work is completed for the outer plate of the hull, additional welding work has to be done on the inner plate. Then, a painting defect can be caused by the effect of burn damage on the other side of the welding part where painting work has already been finished.
Currently for burn damage on a painted surface, the ship owner or the register requests a repair work after re‐docking, and this results in an additional cost. A defect caused by burn damage involves various variables including welding speed, material, heat input, temperature on the other side, and the worker’s skill. Of these variables, material is a fixed variable rather than a mechanical property or the worker’s skill, and the thickness and temperature of material play a significant role in the effect of burn damage.
Recently, materials are setting thinner for the light weight of ships. If a painting defect caused by burn damage is visible with the naked eye it has to be repaired, but if not, quantitative research data are necessary. A long‐term purpose of painting is the prevention of corrosion. For this reason, it is required to analyze long‐term data on corrosion prevention according to the effect of burn damage on painted surface.
This study was conducted in order to examine the effect of burn damage and resultant anti‐corrosion performance. The breakdown and defect of paint film caused by burn damage are considered to affect not only macroscopically but also the adhesive force and anti‐corrosion performance of the paint film. The material of paint film was epoxy paint that is used most widely for heavy‐duty coating, and in order to prepare burn damage, heat treatment using a torch was applied to the other side of painting.
Surface and chemical structure charge according to aging was analyzed using measuring FE‐SEM and using infrared absorption spectroscopy, and variation in anti‐corrosion performance was analyzed through AC impedance test.
Keywords : Burn damage, temperature, FT-IR, EIS, anti-corrosion evaluation, epoxy paint.
- Author(s)
- 서창호
- Issued Date
- 2015
- Awarded Date
- 2015. 2
- Type
- Dissertation
- Publisher
- 부경대학교 대학원
- URI
- https://repository.pknu.ac.kr:8443/handle/2021.oak/11808
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001967427
- Alternative Author(s)
- Seo, Chang ho
- Affiliation
- 대학원
- Department
- 대학원 공업화학과
- Advisor
- 박진환
- Table Of Contents
- 1. 서 론 1
2. 이론적 배경 3
2.1 유기도막에 의한 방식 기구 3
2.2 유기도막의 노화 메커니즘 7
2.2.1 물의 침투성과 도막하 부식 7
2.2.2 음극박리 (Cathodic delamination) 9
2.3 에폭시 수지 도료 10
2.3.1 에폭시 수지의 경화 및 반응 메커니즘 10
2.3.2 Bisphenol A형 Epoxy 수지 13
2.4 Burn damage 15
2.5 교류 임피던스 측정법 17
2.5.1 교류 임피던스의 기초 17
2.5.2 교류 임피던스의 측정 원리 23
2.5.3 물 흡수에 의한 도막내부의 임피던스 특성 25
2.5.4 물의 유전율 27
2.5.5 임피던스 측정에 의한 흡수 거동의 고찰 28
2.5.6 교류 임피던스 측정 결과 도시 방법 31
2.5.7 교류 임피던스법의 측정 원리 37
2.5.8 도막의 노화에 따른 등가회로와 교류 임피던스 diagram 40
3. 실험방법 43
3.1 시험편 제작 43
3.2 재 료 44
3.2.1 Epoxy 수지 44
3.3 열처리 및 시험편 명 46
3.4 가속 노화 시험 49
3.4.1 내식성 평가에 대한 가속 노화 시험 49
3.4.2 염수 분무 시험(Salt spray test) 49
3.5 평가 시험 51
3.5.1 색차 측정 시험 51
3.5.2 FE-SEM 측정 54
3.5.3 FT-IR(Spectrophotometer) 분석 56
3.5.3.1 전자기 복사선을 이용한 분광법 56
3.5.3.2 적외선 분광법 58
3.5.3.3 적외선 흡수 58
3.5.3.4 KBr pellet 59
3.5.4 교류 임피던스 측정 61
3.5.5 도막 부착력 시험 63
4. 결과 및 고찰 65
4.1 소재 두께에 따른 표면 온도 관찰 65
4.2 Color guide에 의한 도막 표면의 색차 측정 70
4.3 FE-SEM에 의한 도막과 소재의 단면 관찰 73
4.4 FT/IR-KBr pellet에 의한 도막 흡광도 측정 79
4.5 에폭시 도막의 임피던스 특성 변화 82
4.5.1 Burn damage 온도 별 에폭시 도막의 임피던스 측정 82
4.5.1.1 소재 두께 5mm Burn damage 시험편에 대한 임피던스 측정 83
4.5.1.2 소재 두께 15mm Burn damage 시험편에 대한 임피던스 측정 90
4.6 에폭시 도막의 부착력 측정 97
5. 결 론 100
References 103
- Degree
- Master
-
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