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수분산 polyaspartic 수지와 blocked isocyanate를 이용한 친환경 코팅제의 제조 및 물성

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Alternative Title
Preparation and physical properties of eco-friendly coating agent using waterborne polyaspartic and blocked isocyanate
Abstract
Polyaspartic coating is well known as one of popular eco-friendly coatings because of non VOC and excellent mechanical properties such as fast curing, abrasion resistance, chemical resistance, light resistance and so on. Despite of a number of advantages applying polyaspartic coating to industries, there are limitations to replace conventional polyurea coatings and waterborne coatings in particularly continuous processing lines because of its very short pot-life and relatively high price. To improve short pot-life, polyaspartic resin was dispersed in water using emulsifier and blocked isocyanate as a curing agent. was used. The curing reaction between -NH of aspartics and -NCO of blocked isocyanate and properties of coatings were analysed by measuring viscosity, pencil hardness, FT-IR, weatherometer, yellowing, etc. The results showed that the pot life of waterborne polyaspartic coating agent became longer than that of conventional polyaspartic one without the change in light resistance. These results indicate that newly developed waterborne polyaspartic coating agent could replace current waterborne polyurethane coating agent without the change of the equipments.
Author(s)
박진욱
Issued Date
2017
Awarded Date
2017. 2
Type
Dissertation
Keyword
polyaspartic blocked isocyanate 친환경 코팅제 도료 polyurea 폴리아스파틱 폴리우레아 블록이소시아네이트
Publisher
부경대학교 산업대학원
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/13718
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002331882
Affiliation
부경대학교 산업대학원
Department
산업대학원 응용화학공학과
Advisor
이원기
Table Of Contents
I. 서 론 3
II. 이론적 배경 4
II-1. 도료 이론 4
II-1-1. 기본 개념 4
II-1-2. 도료의 기능 5
II-1-3. 도료의 분류 6
II-1-4. 현대 공업 사회에서 요구되는 도료의 성능 7
II-1-5. 친환경 도료의 종류 9
II-1-6. 수용성 도료 11
II-1-7. VOC 규제 및 대응 13
II-2. Polyaspartic 코팅 22
II-2-1. 기본 개념 22
II-2-1-1. Aspartic acid ester 24
II-2-1-2. Isocyanate 28
II-2-1-3. Blocked isocyanate 32
II-2-2. Polyaspartic polyurea reaction 35
II-2-3. Polyaspartic 코팅제의 장/단점 37
II-2-4. 기존 코팅과의 비교 38
II-3. 수분산화에 대한 이해 40
II-3-1. 기본 개념 40
II-3-2. 수분산 방법 41
II-3-3. 수분산 코팅의 특징 42
III. 실 험 44
III-1. 시약 및 재료 45
III-2. 수분산 polyaspartic 수지 제조 46
III-3. Polyaspartic 코팅제의 제조 51
III-4. 코팅 및 시편 준비 52
III-5. 코팅제의 분석 53
III-5-1. 구조 분석 53
III-5-2. 가사시간 측정 53
III-6. 물성 측정 55
III-6-1. Tack free time & 황변성 확인 55
III-6-2. 내광성 테스트 55
IV. 결과 및 고찰 57
IV-1. 코팅제의 분석 57
IV-1-1. 가사 시간 측정 57
IV-1-2. 구조 분석 62
IV-2. 물성 측정 65
IV-2-1. Tack-free time & 황변성 확인 65
IV-2-2. 내광성 테스트 67
V. 결 론 71
VI. 참고 문헌 73
감사의 글 76
Degree
Master
Appears in Collections:
산업대학원 > 응용화학공학과
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