에너지 전환 및 저장용 질소 도핑된 그래핀의 합성 및 특성 분석
- Alternative Title
- Synthesis and Characterization of Nitrogen-doped Graphene for Energy Conversion and Storage
- Abstract
- As the times growth, energy exhaustion and environmental problems have emerged due to high energy consumption. In order to solve these problems, development of eco-friendly and highly efficient new energy materials was required.
Recently, nitrogen-doped graphene (NG) has attracted great interest due to exotic properties , such as high conductivity, excellent catalytic properties, and tunable electronic structures, which can be used as materials for energy conversion and storage application.
This study reports synthesis of pyridine-N doped graphene (PY-NG) by using an acid-catalyzed dehydration reaction between graphene oxide and 3,4-diaminopyridine. In addition, the restoration of graphitic structure and the electrical properties were confirmed by diverse analytical techniques [X-Ray Diffractometer (XRD), Raman spectroscopy, Thermo gravimetric analysis (TGA), Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), Linear sweep voltammetry (LSV), etc. for supercapacitor and electrocatalysts application.
As a result, PY-NG with optimized nitrogen content was obtained in graphitic network. Therefore, this study can provide a pivot for the development of new energy materials and future researches.
- Author(s)
- 이민석
- Issued Date
- 2017
- Awarded Date
- 2017. 2
- Type
- Dissertation
- Keyword
- 그래핀 질소도핑 그래핀
- Publisher
- 부경대학교 대학원
- URI
- https://repository.pknu.ac.kr:8443/handle/2021.oak/13735
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002332290
- Affiliation
- 부경대학교 대학원
- Department
- 대학원 공업화학과
- Advisor
- 장동욱
- Table Of Contents
- 제 1 장 서 론 1
제 2 장 이론적 배경 및 문헌 조사 4
2.1. 그래핀의 정의 및 특징 4
2.2. 그래핀 옥사이드 4
2.3. 슈퍼커패시터 8
2.4. 연료전지 및 산소환원 반응 10
제 3 장 실 험 13
3.1. 재료 및 시약 13
3.2. 에너지 소재용 피리딘 질소 도핑 그래핀 (PY-NG)의 제조 13
3.3. 분석 14
3.3.1 구조 특성 분석 14
3.3.2 전기적 특성 분석 15
제 4 장 결과 및 고찰 16
4.1. 구조 분석 결과 16
4.1.1. 합성 계략도 16
4.1.2. Elemental analysis (EA) 17
4.1.3. Thermo gravimetric analysis (TGA) 19
4.1.4. Raman spectroscopy 19
4.1.5. X-ray diffraction (XRD) Patterns 22
4.1.6. X-ray photoelectron spectroscopy (XPS) 24
4.1.7. Field emission scanning electron (FE-SEM) and Field emission transmission electron (FE-TEM) microscopies 29
4.2. 슈퍼커패시터에서의 전기적 특성과 Brunauer-Emmett-Teller (BET) 분석 32
4.2.1. Cyclic Voltammetry (CV) 32
4.2.2. Galvanostatic Charge-Discharge (GCD) 35
4.2.3. Brunauer-Emmett-Teller (BET) 36
4.2.4. Electrical conductivity 42
4.2.5. Stability test 44
4.3. 산소환원 반응을 위한 전기 촉매 활성 45
4.3.1. Cyclic Voltammetry (CV) 45
4.3.2. Linear-sweep voltammetry (LSV) 49
제 5 장 결론 60
참고문헌 62
감사의 글 71
- Degree
- Master
-
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- 대학원 > 공업화학과
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