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에너지 전환 및 저장용 질소 도핑된 그래핀의 합성 및 특성 분석

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Alternative Title
Synthesis and Characterization of Nitrogen-doped Graphene for Energy Conversion and Storage
Abstract
As the times growth, energy exhaustion and environmental problems have emerged due to high energy consumption. In order to solve these problems, development of eco-friendly and highly efficient new energy materials was required.
Recently, nitrogen-doped graphene (NG) has attracted great interest due to exotic properties , such as high conductivity, excellent catalytic properties, and tunable electronic structures, which can be used as materials for energy conversion and storage application.
This study reports synthesis of pyridine-N doped graphene (PY-NG) by using an acid-catalyzed dehydration reaction between graphene oxide and 3,4-diaminopyridine. In addition, the restoration of graphitic structure and the electrical properties were confirmed by diverse analytical techniques [X-Ray Diffractometer (XRD), Raman spectroscopy, Thermo gravimetric analysis (TGA), Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), Linear sweep voltammetry (LSV), etc. for supercapacitor and electrocatalysts application.
As a result, PY-NG with optimized nitrogen content was obtained in graphitic network. Therefore, this study can provide a pivot for the development of new energy materials and future researches.
Author(s)
이민석
Issued Date
2017
Awarded Date
2017. 2
Type
Dissertation
Keyword
그래핀 질소도핑 그래핀
Publisher
부경대학교 대학원
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/13735
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002332290
Affiliation
부경대학교 대학원
Department
대학원 공업화학과
Advisor
장동욱
Table Of Contents
제 1 장 서 론 1
제 2 장 이론적 배경 및 문헌 조사 4
2.1. 그래핀의 정의 및 특징 4
2.2. 그래핀 옥사이드 4
2.3. 슈퍼커패시터 8
2.4. 연료전지 및 산소환원 반응 10
제 3 장 실 험 13
3.1. 재료 및 시약 13
3.2. 에너지 소재용 피리딘 질소 도핑 그래핀 (PY-NG)의 제조 13
3.3. 분석 14
3.3.1 구조 특성 분석 14
3.3.2 전기적 특성 분석 15
제 4 장 결과 및 고찰 16
4.1. 구조 분석 결과 16
4.1.1. 합성 계략도 16
4.1.2. Elemental analysis (EA) 17
4.1.3. Thermo gravimetric analysis (TGA) 19
4.1.4. Raman spectroscopy 19
4.1.5. X-ray diffraction (XRD) Patterns 22
4.1.6. X-ray photoelectron spectroscopy (XPS) 24
4.1.7. Field emission scanning electron (FE-SEM) and Field emission transmission electron (FE-TEM) microscopies 29
4.2. 슈퍼커패시터에서의 전기적 특성과 Brunauer-Emmett-Teller (BET) 분석 32
4.2.1. Cyclic Voltammetry (CV) 32
4.2.2. Galvanostatic Charge-Discharge (GCD) 35
4.2.3. Brunauer-Emmett-Teller (BET) 36
4.2.4. Electrical conductivity 42
4.2.5. Stability test 44
4.3. 산소환원 반응을 위한 전기 촉매 활성 45
4.3.1. Cyclic Voltammetry (CV) 45
4.3.2. Linear-sweep voltammetry (LSV) 49
제 5 장 결론 60
참고문헌 62
감사의 글 71
Degree
Master
Appears in Collections:
대학원 > 공업화학과
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