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천연응집제를 이용한 미세조류의 응집특성

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Abstract
Although coagulation-flocculation is effective and widely used, existing metal based coagulants have negative effects on the environment and human body. This study tries to reveal the possibility of using plan based natural coagulants to replace the metal based coagulants such as Alum.
Chitosan and Polyglutamin coagulants were chosen as natural coagulants for this study and the experiments. Response Surface Methodology(RSM) was used for the design of this research and the dose of coagulant and a range of pH were determined for the experiments by RSM.

The experiments using Chitosan was carried out with a range of pH 4.95~10.0 and coagulant dose 40~160mg/L. Through the optimization process by using RSM, it was found that the optimum condition was when the coagulant dose of 105mg/L at pH 7.3, and the micro-algae removal efficiency(as OD660) was 79.2%.

The other experiments using Polyglutamin was conducted with a range of pH 4.5~9, coagulant dose 10~150mg/L. The optimum condition of Polyglutamin coagulation/flocculation was when the coagulant dose of 115mg/L at pH 7.5, and the micro-algae removal efficiency(as OD660) was almost 100%.

Key word: coagulation/flocculation, Chitosan, Polyglutamin, OD660, pH, coagulant dose
Author(s)
김요한
Issued Date
2017
Awarded Date
2017. 2
Type
Dissertation
Keyword
미세조류 응집제
Publisher
부경대학교 대학원
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/13798
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002334012
Affiliation
부경대학교 대학원
Department
대학원 U-EcoCity협동과정
Advisor
이병헌
Table Of Contents
제 1 장 서 론 1
제 2 장 문 헌 연 구 3
2.1 조류, 미세조류 3
2.2 응집의 정의 및 매커니즘 6
2.2.1 이중층 압축 7
2.2.2 흡착과 전하중화 9
2.2.3 체거름 응집 11
2.3 응집제 13
2.4 반응표면법 15
제 3 장 실험재료 및 방법 20
3.1 실험재료 및 장치 20
3.2 천연 응집제를 이용한 조류응집 실험설계 23
3.3 실험방법 및 조류의 분석 25
3.3.1 조류의 응집실험 방법 25
3.3.2 Sedgewick Rafter Chamber를 이용한 cell count 26
3.3.3 미세조류 측정을 위한 UV/VIS-spectrophotometer 27
3.4 OD660과 조류수의 상관관계 28
제 4 장 결과 및 고찰 31
4.1 Chitosan을 이용한 조류제거 31
4.1.1 Chitosan 주입량 및 pH에 따른 OD660 변화 31
4.1.2 Chitosan 주입량 및 pH에 따른 OD660 반응모델추정 35
4.2 Polyglutamin을 이용한 조류제거 40
4.2.1 Polyglutamin 주입량 및 pH에 따른 OD660 변화 40
4.2.2 Polyglutamin 주입량 및 pH에 따른 OD660 반응모델추정 43
4.3 천연응집제에 의한 조류제거 최적화 48
4.3.1 반응표면분석 모델을 이용한 천연응집제의 조류제거 최적화 48
제 5 장 결 론 50
참고문헌 51
Degree
Master
Appears in Collections:
대학원 > U-EcoCity 협동과정
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