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Pre-coated metal용 UV경화형 수지의 조성과 온도에 따른 물성

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Alternative Title
Properties of UV curable resins for pre-coated metal on composition and temperature
Abstract
To expand their applications, UV-curable coatings for pre-coated metal (PCM) require high flexibility and stiffness for formability and hardness, respectively. However, it is difficult to satisfy both properties of coatings. Therefore, this study was focused on each factor which affects the properties of UV-cured coatings or PCM. The curing conversion of UV-cured coatings was improved in oxygen-free atmosphere. The optimum UV irradiation for curing was 1500 mJ/cm2. Both mechanical and thermal properties were dependent on the degree of crosslinking. Tensile strength was increased and elongation was decreased, according to the degree of crosslinking. This results in hardness was increased and formability was reduced. UTM and erichsen cupping test were performed at different temperatures to improve poor formability. As the temperature raise, the tensile strength was decreased, but elongation was widely enhanced. The results showed that the formability was much improved at an elevated temperature due to the increased flexibility.
Author(s)
배성국
Issued Date
2018
Awarded Date
2018.2
Type
Dissertation
Keyword
PCM UV경화 코팅 도막 물성
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/13938
http://pknu.dcollection.net/common/orgView/200000010789
Alternative Author(s)
Seong-Guk Bae
Affiliation
부경대학교 대학원
Department
대학원 고분자공학과
Advisor
이원기
Table Of Contents
Content i
List of Tables iii
List of Figures iv
Abstract vi
1. 서론 1
2. 이론적 배경 4
2.1. UV 경화 4
2.1.1. 특징 4
2.1.2. UV 경화에 영향을 주는 인자 6
2.1.3. 전환율 9
2.2. UV 경화형 도료 10
3. 실험 17
3.1. 재료 17
3.2. UV 경화형 도료의 배합 18
3.3. UV 경화 19
3.4. 측정 21
4. 결과 및 고찰 24
4.1. 경화특성 24
4.1.1. 경화 분위기와 광량에 따른 분석 24
4.1.2. 도막 두께가 전환율 미치는 영향 30
4.2. 조성에 따른 물성 31
4.2.1. 기계적 물성 31
4.2.2. 열적 특성 36
4.2.3. 부착성 37
4.2.4. 내 스크래치성 38
4.2.5. 성형성 39
4.3. 온도에 따른 물성 변화 40
4.3.1. 기계적 성질 40
4.3.2. 성형성 48
5. 결론 50
참고문헌 53
Degree
Master
Appears in Collections:
대학원 > 고분자공학과
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