PUKYONG

OTFT용 Pyrene유도체의 합성 및 전하 이동 특성

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Abstract
These days, IT and electronics industry, with conductive organic diodes and transistors have become a big issue, researchers and engineers related to ongoing research activities carried out technical development and industrial scale is gradually being largely. Among them, the organic electronic device using a variety of materials and light, thanks to the flexible nature makes it easy to create in the form of fibers or films. As a result, organic thin-film transistors(OTFT) technology is an electronic device that we should pay attention to. The organic thin film transistor technology in the late 1970s, accidentally balls that are characteristic of the semiconductor liquid organic polymer poly-acetylene was developed using organic semiconductor research was in earnest. As a result, the current organic thin-film transistors bendable organic light-emitting diodes(Organic Lighting Emitting Diodes: OLEDs), electronic paper(E-paper), a switch for active matrix display device, integrated circuit that contains a smart card, ID card, etc. of steps that can be applied to virtually reached. The interest in organic thin-film transistors as compared to other transistor, and is attributed by many advantages.
Compared with the existing inorganic TFT, the production process is simple, and can be produced by a large area of the device is easy mass production artist. And less expensive, and not easily broken by the impact can bend or fold . As above, the future of the industry as an integral part of the display has the advantage that it, infinite products have the potential enemy.
Author(s)
김종욱
Issued Date
2014
Awarded Date
2014. 2
Type
Dissertation
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/1398
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001966807
Affiliation
대학원
Department
대학원 인쇄공학과
Advisor
손세모
Table Of Contents
목 차


목 차 ⅰ
List of Figures ⅴ
List of Tables ⅷ
List of Schemes ⅸ

Abstract ⅹ

1. 서 론 1

2. 이 론 3
2-1. 유기 박막 트랜지스터(Organic Thin Film Transistor, OTFT)의 구조 3
2-2. 유기 박막 트랜지스터(OTFT)의 구동원리 4
2-3. 유기 박막 트랜지스터(OTFT)의 재료 7
2-4. 유기 박막 트랜지스터(OTFT)의 유기 반도체층 제작 공법 8
2-5. 유기 박막 트랜지스터(OTFT)의 성능 요소 10

3. 실 험 13
3-1. 합성 시약 13
3-2. Heteroacene(HA) 유도체 합성 14
3-2-1. Heteroacene 1의 합성 14
3-2-1-1. 1-Borate pyrene의 합성(1) 14
3-2-1-2. 1-(2-Nitrophenyl)pyrene의 합성(2) 15
3-2-1-3. 7H-phenaleno[1,9-bc]carbazole의 합성(3) 16
3-2-2. Heteroacene 2의 합성 17
3-2-2-1. N-phenylpyren-1-amine의 합성(1) 17
3-3. Organic semiconductor(PD) 유도체 합성 18
3-3-1. Organic semiconductor(PD)1, 2의 합성 18
3-3-1-1. 7-Phenyl-7H-phenaleno[1,9-bc]carbazole(PD1)의 합성(1) 19
3-3-1-2. N,N-diphenylpyren-1-amine(PD2)의 합성(2) 20
3-3-2. Organic semiconductor(PD)3, 4의 합성 21
3-3-2-1. 7-(Pyridin-2-yl)-7H-phenaleno[1,9-bc]carbazole(PD3)의 합성(1) 22
3-3-2-2. N-(biphenyl-4-yl)-N-phenylpyren-1-amine (PD4)의 합성(2) 23
3-3-3. Organic semiconductor(PD)5, 6의 합성 24
3-3-3-1. 7-(4-(Pyridin-3-yl)phenyl)-7H-phenaleno[1,9-bc]carbazole(PD5)의 합성(1) 24
3-3-3-2. N-phenyl-N-(4-(pyridin-3-yl)phenyl)pyren-1-amine(PD6)의 합성(2) 25
3-4. 합성물의 분석 및 측정 26
3-4-1. 1HNMR 스펙트럼 26
3-4-2. DSC(Differential Scanning Calorimetry) 26
3-4-3. 광학적 특성평가 27
3-4-4. 순환 전압 전류(Cyclic Voltammetry) 측정 27
3-4-5. 전하이동도(Mobility) 측정 27

4. 결과 및 고찰 28
4-1.유기 반도체 재료의 합성 28
4-2.유기 화합물의 분광특성 29
4-2-1. 7H-phenaleno[1,9-bc]carbazole(HA1)의 분광특성 30
4-2-2. N-phenylpyren-1-amine(HA2)의 분광특성 31
4-2-3. 7-Phenyl-7H-phenaleno[1,9-bc]carbazole(PD1)의 분광특성 32
4-2-4. N,N-diphenylpyren-1-amine(PD2)의 분광특성 33
4-2-5. 7-(Pyridin-2-yl)-7H-phenaleno[1,9-bc]carbazole(PD3)의 분광특성 34
4-2-6. N-(Biphenyl-4-yl)-N-phenylpyren-1-amine(PD4)의 분광특성 35
4-2-7. 7-(4-(Pyridin-3-yl)phenyl)-7H-phenaleno[1,9-bc]carbazole(PD5)의 분광특성 36
4-2-8. N-phenyl-N-(4-(pyridin-3-yl)phenyl)pyren-1-amine(PD6)의 분광특성 37
4-3. 유기 화합물의 열적 안정성 38
4-4. 유기 화합물의 전기적 특성 40
4-4-1. 순환 전압 전류(Cyclic Voltammetry, CV) 40
4-4-2. 전하이동도(Mobility) 44

5. 결 론 46

6. References 48
Degree
Master
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