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블록공중합체 마이셀을 이용한 에너지 포획형 나노구조의 형성과 촉매 응용

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Abstract
In selective solvent, diblock copolymers self-associate into spherical micelles consisting of soluble coronas and insoluble cores. Since the chemical properties of core and corona are different from each other, they can be functionalized as different particles. In this study, we synthesize two different metal nanoparticles in PS-PAA micelles to form heterogenous nanoparticle assembly. In particular, we tried to separated gold nanoparticle and silver nanoparticle in different domains to combined both plasmonic and catalitic properties .Catalytic of formed self assembly micelle is evaluated by 4-nitrophenol reduction.
Author(s)
제남진
Issued Date
2017
Awarded Date
2017. 8
Type
Dissertation
Keyword
diblock copolymers micelles self-associate
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/14397
http://pknu.dcollection.net/common/orgView/000002381608
Alternative Author(s)
Energy-harvesting nanostructures by block copolymermicelles and their catalytic application
Affiliation
부경대학교 대학원
Department
대학원 고분자공학과
Advisor
유성일
Table Of Contents
제 1 장 서론 1
제 2 장 이론적 배경 4
2-1.금속 나노입자 4
2-2. 표면 플라즈몬 6
2-3. 블록공중합체 10
2-4. 이중 블록공중합체 마이셀 자기조립체 11
2-5. 은 나노입자 17
2-6.광촉매 18
제 3 장 실험 17
3-1. 재료 17
3-2. Au 나노입자 표면개질 및 Au 나노입자 도입 18
3-3. 이종나노입자 합성 20
3-4. 광열특성 측정 22
3-5. 촉매특성 측정 23
제 4 장 결과 및 고찰 24
4-1. 이종 나노입자 24
4-2. 광열특성 32
4-3. 촉매특성 34
제 5 장 결론 45
참고문헌 46
Degree
Master
Appears in Collections:
대학원 > 고분자공학과
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