PUKYONG

무기징크 도료에서의 亞鉛 含量에 따른 防蝕性能 硏究

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Abstract
Abstract

Inorganic coating are widely used to control the corrosion of metal. The main function of anticorrosive coating is to prevent corrosive agents, such as water or oxygen, from contacting the underlying metal substrate. In addition, the inorganic coating function as high resistance between anode and cathode of local corrosion cell. The anticorrosive performance of inorganic coating can be obtained by the functions of binder and pigment, and latter is known to be more important.
Inorgainc zinc-rich primer, top coat(epoxy) were tested on their electrochemical characteristics with EIS.
First, ethyl silicate and zinc wt.% Content by applying a primer, and then was applied followed by a subsequent epoxy.
Zinc content in order to study the characteristics of the cathodic protection to the open circuit potentials were measured, and the corrosion protection coating system to study the performance of the AC impedance was measured.
Artificial sea water immersion test and continuous neutral salt spray test were conducted find out deteriorations of the coating system during 40 days. In addition, corrosion potentials of zinc-rich were measured to figure out whether the steel was cathodic protected.
As a result, the passage of time according to an accelerated aging test as applied to inorganic zinc-rich primer according to the increase in the zinc content of the cathodic protection coating system characteristics and the correlation between could research.

Keyword : inorginc coating, zinc-rich primers, electrochemical properties. EIS, corrosion potential
Author(s)
이승아
Issued Date
2014
Awarded Date
2014. 2
Type
Dissertation
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/1501
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001966910
Affiliation
대학원
Department
대학원 공업화학과
Advisor
박진환
Table Of Contents
1. 서론
2. 이론적 배경
2.1 무기질 아연말 도료의 개요
2.1.1 Zinc silicate coating의 경화 구조
2.1.2 무기질 아연말 도료의 일반적인 성질
2.2 유기 도막의 방식 특성
2.3 음극방식
2.4 유기 도막의 부식 메커니즘
2.4.1 물의 침투성과 도막하부 부식
2.4.2 Wet adhesion/Osmosis/blistering
2.4.3 음극박리 (Cathodic delamination)
2.5 교류 임피던스에 대한 이론
2.5.1 교류 임피던스의 이론
2.5.2 부식계의 등가회로와 교류 임피던스 특성
2.5.3 교류 임피던스법의 측정 원리
2.5.4 도막의 노화에 따른 등가회로와 교류 임피던스 diagram
3. 실험방법
3.1 시험편 제작
3.2 가속열화시험
3.2.1 염수분무시험
3.2.2 해수침지시험
3.3 도막의 방식성능 평가
3.3.1 개회로 전위 측정
3.3.2 교류임피던스 측정
3.3.2 도막 부착력 시험
4. 결과 및 고찰
4.1 무기질 아연말 도막의 개회로 전위 변화
4.1.1 아연 함량에 따른 개회로 전위 변화
4.1.2 가속 열화시험에 따른 개회로 전위 변화
4.2 가속열화 시험에 따른 임피던스 특성 변화
4.2.1 Zinc dust 함량에 따른 임피던스 특성 변화
4.2.2 해수침지시험에 따른 임피던스 특성 변화
4.2.3 염수분무시험에 따른 임피던스 특성 변화
4.3 부착력 시험 결과 (Pull-off test)
5. 결론
Reference
Degree
Master
Appears in Collections:
대학원 > 공업화학과
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