PUKYONG

A Study of Porous Polydimethylsiloxane/Au Nanoparticle Composites and Their Photothermal Conversion

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Abstract
Solar energy-based photothermal conversion systems have attracted increasing research interest over the past several decades due to their environmentally friendly, sustainable and versatile advantages. Recent studies have reported strategies for achieving high energy conversion efficiencies using plasmon metal nanoparticles-based solar absorbers. In this study, porous polymers with multiple scattering properties and gold nanoparticles were composited using a simple and efficient method for high-performance solar harvesting. The prepared porous Polydimethylsiloxane (PDMS) polymer was immersed in HAuCl4 solution to synthesize gold nanoparticles without additional reducing agent. Finally, the prepared PDMS/Au nanoparticle composite was irradiated with a stimulated sun light to induce photothermal conversion, and the generated heat was applied to the thermoelectric power generation system.
Author(s)
이건석
Issued Date
2021
Awarded Date
2021. 2
Type
Dissertation
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/2121
http://pknu.dcollection.net/common/orgView/200000372301
Affiliation
부경대학교 대학원
Department
대학원 화학융합공학부
Advisor
유성일
Table Of Contents
Chapter I. Introduction 1
I-1. Energy Harvesting 1
I-1.1. Solar Energy Harvesting 1
I-2. Gold Nanoparticle 3
I-2.1. Localized Surface Plasmon Resonance 3
I-2.2. Photothermal Effect 5
I-3. Porous Polymer 5
I-4. Thermoelectric Power Generation 8
Chapter II. Fabrication of PDMS/Au Sponges and Their Photochemical Reactions 10
II-1. Introduction 10
II-2. Experimental Section 13
II-2.1. Material 13
II-2.2. Procedure 13
II-2.2.1. Fabrication of PDMS Sponge 13
II-2.2.2. Modification of PDMS Sponge 14
II-2.2.3. Fabrication of Thermoelectric Device 14
II-2.3. Measurement 14
II-3. Result and Discussion 15
II-3.1. Characteristic of PDMS/Au Sponge 15
II-3.2. Photothermal Effect of PDMS/Au Sponge 25
II-3.3. Thermoelectric Power Generation 32
II-4. Conclusion 39
References 40
Acknowledgments 43
Degree
Master
Appears in Collections:
대학원 > 화학융합공학부
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