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LAS(Lithium-Aluminosilicate) 순환물질 침출 잔사 내 제올라이트를 이용한 Mg-Zeolite 개질 및 중금속 흡착 제거 연구

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Alternative Title
A Study on Mg-Zeolite modification and removal of heavy metal using zeolite in LAS (Lithium-Aluminosilicate) leaching residue
Abstract
Due to the recent industrial development, water pollution is getting serious. Water pollution is becoming serious due to industrial wastewater generated from factories. The main cause of water pollution from industrial wastewater in factories is pollution by heavy metals. Heavy metals have a very harmful effect on the human body. Therefore, industrial wastewater must be discharged after passing the discharge allowance standard. Various methods are being studied for the removal of heavy metals in industrial wastewater. Recently, a lot of research is underway as a method of removing using zeolite using adsorption properties.
In this study, zeolite existing in the leaching residue of LAS (Lithium-Aluminosilicate) recycled resources, which is a kind of glass & ceramic emerging as a substitute for lithium raw materials, was used as the main raw material.
First, a reforming process experiment was conducted with Mg-Zeolite, which has excellent adsorption capacity, and an optimal reforming study was conducted. After that, a test wastewater solution was prepared and a study on the adsorption and removal of contaminants present in industrial wastewater was conducted with the modified Mg-Zeolite.
In addition, in order to obtain only pure zeolite in the LAS leaching residue, a lithium compound was converted into lithium sulfate to further remove lithium, and a method for recovering lithium from the LAS recycled material was also devised.
Author(s)
김규철
Issued Date
2021
Awarded Date
2021. 2
Type
Dissertation
Keyword
LAS(Lithium-Aluminosilicate) 순환물질 제올라이트 중금속 흡착 제거
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/2182
http://pknu.dcollection.net/common/orgView/200000368985
Alternative Author(s)
Gyu-Cheol Kim
Affiliation
부경대학교 대학원
Department
대학원 금속공학과
Advisor
왕제필
Table Of Contents
Ⅰ. 서론 1
1.1 연구배경 1
Ⅱ. 이론적 배경 4
2.1 LAS(Lithium-Aluminosilicate)의 개요 4
2.2 제올라이트의 개요 5
2.3 제올라이트의 특성 8
2.3.1 흡착 특성 8
2.3.2 촉매 특성 9
2.3.3 탈수 및 재흡수 특성 10
2.4 제올라이트의 이온교환성 10
Ⅲ. 실험방법 및 결과 13
3.1 연구방법 13
3.1.1 개요 13
3.1.2 실험재료 13
3.2 시료의 분석 16
3.2.1 상용 제올라이트와 침출 잔사 내 제올라이트 분석 16
3.3 Mg-Zeolite 개질 방법 연구 20
3.3.1 Mg-Zeolite 개질 공정 Test 20
3.4 중금속용액 흡착능 측정 31
3.4.1 중금속 용액 제조 31
3.4.2 흡착능 측정 방법 및 결과 32
3.5 침출 잔사 내 리튬화합물 제거 연구 33
3.5.1 개발의 필요성 33
3.5.2 실험 방법 36
3.5.3 리튬화합물 제거 결과 36
Ⅳ. 결론 50
Ⅴ. 참고문헌 52
Degree
Master
Appears in Collections:
대학원 > 금속공학과
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