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그래핀 표면 기능화와 이를 이용한 폴리이미드, 폴리아믹산 하이브리드 물질 합성 및 특성 평가

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Alternative Title
Synthesis and Characterization of Polyimide, Polyamic Acid Hybrid materials using Surface Functionalized Graphene
Abstract
In this study, Forming of organic - inorganic hybrid material experiment was carried out. First, surface functionalized graphene was synthesized through the graphene oxide surface reduction. Imide moieties were attached to amine - surface functionalized graphene using a step-by-step condensation and thermal imidization method. Second, transparent Polyimide (PI), Polyamic Acid (PAA) was prepared by a step growth polymerization of diamine monomer and dianhydride monomer. Finally, each obtained material was mixed together by using organic solvent. The solution was then spin-coated on a cleaned glass substrate and totally organic - inorganic hybrid material layer was successfully casted.
Author(s)
박한은
Issued Date
2020
Awarded Date
2020. 2
Type
Dissertation
Keyword
graphene graphene oxide polyimide graphene functionalization organic-inorganic hybrid material
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/23811
http://pknu.dcollection.net/common/orgView/200000292506
Alternative Author(s)
Han Eun Park
Affiliation
부경대학교 대학원
Department
대학원 융합디스플레이공학과
Advisor
임권택
Table Of Contents
제 Ⅰ장 서 론 1
제 Ⅱ장 이 론 3
1. 그래핀(Graphene) 3
1.1. 그래핀(Graphene) 3
1.2. 그래핀의 전자구조 4
1.3. 그래핀의 특성 5
1.4. 그래핀의 합성 7
2. 폴리이미드(Poly Imide) 9
2.1. 폴리이미드(Poly Imide) 9
2.2. 투명 폴리이미드(Colorless Poly Imide - CPI) 10
2.3. PI의 CTC를 감소시키는 분자구조 11
2.4. CPI를 만들 수 있는 모노머 13
2.5. CPI복합체 필름 제조 방법 15
제 Ⅲ장 실 험 16
1. 시약 16
2. Graphene의 Surface Modificaion 16
2.1. Graphene Oxide(GO) 합성 16
2.2. Amine group Surface Modification of GO 18
2.3. Imide group Surface Modification of GO 18
3. PI 필름의 제조 20
3.1. PI의 합성 20
3.2. 이미드화(Imidization) 21
3.3. Modified Graphene - PI 복합 필름의 제작 23
4.측정방법 및 측정기구 24
제 Ⅳ장 결과 및 고찰 25
1. Modified Graphene의 특성분석 25
1.1. Graphene Oxide(GO) 25
1.2. Amine Group Modified Graphene 27
1.3. Imide Group Modified Graphene 28
2. 투명 폴리이미드(Colorless Polyimide) 31
3. Surface Modified Graphene/PI Hybrid film 32
제 Ⅴ 장 결 론 39
제 Ⅵ 장 참고 문헌 40
Degree
Master
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대학원 > 융합디스플레이공학과
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