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Organic TFT의 고전도성 물질 - 전이금속 산화물 복합체 기반 접촉전극 제조 기술에 관한 연구

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Alternative Title
A Study on the Preparation of Contact Electrode based on High Conductivity material-transition metal oxide Composites for Organic TFT
Abstract
Organic electronic devices have a variety of processes and infinite materials at low cost, which has attracted a lot of research attention due to numerous potential applications. The key to improving the performance of devices such as organic field effect transistors (OTFTs) is to select contact electrode materials that provide efficient charge injection to active channels. The contact electrode affects the active channel; it determines the carrier type in the energy level alignment and manages charge injections associated with the quality of the contact interface to confirm device performance. Au is the most commonly used electrode for source-drain electrode materials, and thin films based on two-dimensional materials such as metal oxides and graphene are attracting attention as alternative electrode materials. However, materials such as Au and graphene are expensive and deposited with relatively complex processes. In addition, because the surface is not good due to the formation of the interfacial dipole layer, there is a considerable charge injection barrier, so research on finding alternative electrode materials should be carried out to avoid these disadvantages. In this study, the contact electrode of OTFTs was implemented by bar coating, which is a relatively simple process using transition metal oxides capable of solution treatment, and electrical and morphological characteristics were analyzed. This study also explored the method of fabricating a transition metal oxide composite as a material for efficient charge transfer of contact electrodes.
Author(s)
이영재
Issued Date
2022
Awarded Date
2022. 2
Type
Dissertation
Keyword
Electrode transition metal oxide Rhenium Rhenium oxide Single wall nanotube Organic thin film transistor
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/24151
http://pknu.dcollection.net/common/orgView/200000607183
Alternative Author(s)
Young Jae Lee
Affiliation
부경대학교 대학원
Department
대학원 스마트그린기술융합공학과
Advisor
백강준
Table Of Contents
Ⅰ. 서 론 1
Ⅱ. 배 경 이 론 3
1. 나노인쇄전자의 발전 3
2. 유기 전계 효과 트랜지스터(OFET) 5
가. OFET 구조 7
나. OFET의 구동원리 및 전기적 특성 9
다. 유기반도체 소재 11
3. 접촉전극재료 14
가. Rhenium(IV) oxide/SWCNT 복합체 17
Ⅲ. 실험 및 측정 21
1. 실험 재료 21
가. Rhenium(IV) oxide/SWCNT 복합체 용액 제조 21
나. Organic Semiconductors 23
2. 실험 방법 24
가. Silicon oxide 기판 세척 24
나. Spray coating을 통한 ReO2/SWCNT 전극 형성 25
다. Spin coating을 통한 고분자 반도체 박막 형성 26
3. 실험 장비 27
가. 라만 측정 장비 (Raman spectroscopy) 27
나. SEM(Scanning Electron Microscope) 분석 장비 29
다. XPS(X-ray Photoelectron Spectroscopy) 분석 장비 30
라. UPS(Ultraviolet Photoelectron Spectroscopy) 분석 장비 32
마. 반도체 소자 분석 장비 34
Ⅳ. 실험 결과 36
1. Raman data 분석 36
2. SEM을 통한 코팅된 표면 특성 분석 38
3. XPS data 분석 40
4. UPS data 분석 42
5. OFET의 전기적 특성 변화 분석 45
V. 결 론 49
참 고 문 헌 51
Degree
Master
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대학원 > 스마트그린기술융합공학과
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