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원통형 압전 진동자를 이용한 ZnO 나노구조물의 성장에 관한 연구

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Alternative Title
Study on Growth of ZnO Nanostructured Materials using Cylindrical Piezoelectric Vibrator
Abstract
Recently, synthesis methods of new nanostuctured materials such as hydrothermal method, vapor-liquid-solid method, chemical vapor deposition and thermal evaporation have attracted a lot of researches. The ZnO nanostuctured materials is especially interested due to their unique structure and size-dependent electrical, optical and mechanical properties.
However, the conventional methods have a various problem such as low crystallinity, long reaction time and limitation of substrate.
In order to solve these problems, in this paper, we designed the ZnO growth device using a cylindrical piezoelectric PZT vibrator. This growth device is suggested for more simple and efficient synthesis method by using focused ultrasound.
To confirm the effectiveness of the device, the results obtained by the cylindrically focused ultrasound were discussed with the non-focused and the hydrothermal systhesis method in different conditions.
As the results, it is shown that the ZnO nanostructured materials grew up well with focused ultrasound comparing with the results without the focusing.
From the results, the validity of the suggested growth method using cylindrically focused ultrasound could be confirmed.
Author(s)
이충화
Issued Date
2012
Awarded Date
2012. 8
Type
Dissertation
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/25235
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001965118
Alternative Author(s)
Lee, Choong Hwa
Affiliation
부경대학교 대학원
Department
대학원 물리학과
Advisor
김무준
Table Of Contents
Abstract ⅴ

Ⅰ. 서론 1

Ⅱ. 초음파 캐비테이션에 의한 ZnO 나노구조물의 합성 메커니즘 5
2.1 초음파 캐비테이션의 발생 원리 5
2.2 초음파 캐비테이션 포화 현상 10
2.3 캐비테이션 버블내에서의 화학반응 11
2.4 ZnO 나노구조물의 초음파 합성 메커니즘 12

Ⅲ. 성장장치의 제작과 특성 14
3.1 원통형 압전 진동자를 이용한 성장장치 제작 14
3.2 원통형 압전 진동자의 전기-음향 변환 효율 19
.
Ⅳ. 성장조건에 따른 결과 22
4.1 전구체의 농도에 따른 ZnO 나노구조물의 성장 22
4.2 위치에 따른 ZnO 나노구조물의 성장 28
4.3 음향파워에 따른 ZnO 나노구조물의 성장 33
4.4 ZnO 나노구조물의 결정구조 분석 37

Ⅴ. 고찰 40
5.1 평면초음파를 이용한 경우 40
5.2 수열합성법을 이용한 경우 45

Ⅵ. 결론 48

참고문헌 51
Degree
Master
Appears in Collections:
대학원 > 물리학과
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