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녹색 및 황색 발광 α, β-phase Zn2SiO4:Mn2+기반 MOS 구조 전계발광소자

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Alternative Title
A Study on Green and Yellow emitting α and β-phase Zn2SiO4:Mn2+ based MOS Structure electroluminescence device
Abstract
A ZnO:Mn phosphor thin film was deposited on si wafer by RF Magnetron Sputtering and them annealed to form a Zn2SiO4:Mn2+ thin film. The structural characteristics of each annealing temperature and characteristics of the light emitting device were studied. In this research, MOS structure device has a thickness of several nm based on a si wafer. Zn2SiO4:Mn2+ 65 nm thick phosphor thin film is formed on the top of p-type si wafer, and alternate current(AC) power is applied between the transparent ITO top-electrode and bottom-electrode(Al). Phosphor thin film deposited ZnO:Mn target on si wafer surfaces by RF Magnetron sputtering, synthesized α-phase, β-phase Zn2SiO4:Mn2+ phosphor thin film by Rapid Thermal Annealing system(RTA), and drove a semiconductor light emitting structure composed of a top electrode ITO-Oxide phosphor layer-silicon substrate. Though AC drive, visible light spectrum with 525 nm from α-phase Zn2SiO4:Mn2+ and β-phase 566 nm from d-d transition of Mn2+ ions. The Vth(Threshold voltage) of the device was 18 Vrms and breakdown occurred at 31 Vrms and it showed exponential increase intensity and curve shape increase current when voltage increases.
Author(s)
백경도
Issued Date
2023
Awarded Date
2023-02
Type
Dissertation
Keyword
Sputtering", "a-phase", "b-phase", "electroluminescence", "Zn2SiO4:Mn2+" , "MOS
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/33032
http://pknu.dcollection.net/common/orgView/200000664230
Alternative Author(s)
GyeongDo Baek
Affiliation
부경대학교 대학원
Department
대학원 융합디스플레이공학과
Advisor
김종수
Table Of Contents
제Ⅰ장 서 론 1

제Ⅱ장 이 론 3
제 1절 PVD(Physical Vapor Deposition) 3
1.1 Sputtering 3
1.2 DC Sputtering 5
1.3 RF Magnetron Sputtering 6
제 2절 형광체(Phosphor) 8
2.1 형광체의 의의 8
2.2 Mn2+ 이온의 에너지 준위, 발광 원리 11
제 3절 MOS(Metal-Oxide-Semiconductor) 전계발광 13
3.1 MOS 정의 13
3.2 전계발광과 응용분야 15
제 4절 MOS 구조 전계발광소자의 구성 16
4.1 발광층 16
4.2 기판 18
4.3 전극 19

제Ⅲ장 실 험 20
제 1절 진공 증착장치 20
1.1 RF Magnetron Sputtering system 구성 20
제 2절 MOS 구조 전계발광소자 제작 22
2.1 ZnO:Mn 타겟 제작 22
2.2 소자 제작 23
제 3절 특성평가 25
3.1 MOS 구조 전계발광소자의 특성평가 25

제Ⅳ장 결과 및 고찰 26
제 1절 구조분석 26
1.1 열처리 온도별 Zn2SiO4:Mn2+ 박막 X-ray diffraction 패턴 26
1.2 FE-SEM 분석 28
1.3 FE-TEM 분석 29
1.4 SPM 분석 32
제 2절 광학적·전기적 특성 33
2.1 EL 스펙트럼 분석 33
2.2 소자의 전압 증가에 따른 특성 37
2.3 Time chart 특성 38

제Ⅴ장 결 론 42
Degree
Master
Appears in Collections:
대학원 > 융합디스플레이공학과
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