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무용제 타입 UV경화형 실버 페이스트 개발

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Alternative Title
Development of Solvent-free type for UV-curable Silver Paste
Abstract
In this study, a solvent-free type UV curing silver paste was developed. In the formulation of the paste, the oligomers, monomers and photoinitiators were all taken the same. Combining the contents of spherical and plate-shaped silver and nano-sized silver prepared a total of 6 types of pastes. It measured the viscosity and viscoelasticity of the prepared paste. Patterns were printed by screen printing, but all were printed under the same printing conditions. After printing, an electrode coating film was formed by UV curing. Six samples were prepared for each paste by varying the exposure dose. It evaluated the conductivity, hardness and adhesion of the prepared samples. It selected the pastes with good results. The curing characteristics of the samples of the selected paste were evaluated by TGA and FT-IR. It evaluated the conductivity improvement by sintering the selected paste with high-intensity pulsed light with a broad spectrum.
Results, the paste with the best conductivity, hardness, adhesion, and curing properties was a silver paste in which spherical silver powder and 10 nm silver powder were mixed in a ratio of 9:1. As a result of sintering, it seems that the dispersion of nano-sized silver is not good. It is judged that if the dispersion problem is improved, the conductivity will be better.
Author(s)
장민용
Issued Date
2023
Awarded Date
2023-02
Type
Dissertation
Publisher
부경대학교
URI
https://repository.pknu.ac.kr:8443/handle/2021.oak/33068
http://pknu.dcollection.net/common/orgView/200000669564
Affiliation
부경대학교 대학원
Department
대학원 나노융합공학과
Advisor
남수용
Table Of Contents
Ⅰ. 서 론 1
Ⅱ. 배경이론 2
1. 무용제 UV 경화 페이스트 2
가. 무용제 UV 경화 페이스트의 정의 2
나. 무용제 UV 경화 페이스트의 구성 3
2. UV 경화 시스템 6
가. UV 경화 시스템의 개요 6
나. UV 경화 원리 7
다. 특징 8
3. 레올로지 9
가. 점도 9
나. 틱소트로피 11
다. 동적점탄성 12
4. 페이스트 제조 및 분산공정 14
5. 스크린인쇄 원리 17
6. 4-point probe로 비저항 측정 19
Ⅲ. 실 험 21
1. 실험방법 21
가. 시료 21
나. 페이스트 제조 24
다. 스크린 인쇄 26
라. UV노광 공정 27
2. 측정방법 28
가. 페이스트의 레올로지 측정 28
나. 인쇄패턴의 비저항 측정 29
다. 인쇄패턴의 연필경도 측정 30
라. 인쇄패턴의 접착력 측정 31
Ⅳ. 결과 및 고찰 33
1. 페이스트의 점도와 점탄성 결과 33
2. 노광량에 따른 전기전도성, 경도, 접착력 차이비교결과 35
3. 페이스트의 FT-IR, TGA, 광소결 평가 결과 39
Ⅴ. 결 론 44
참고문헌 46
Degree
Master
Appears in Collections:
대학원 > 나노융합공학과
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