극전환 전해반응기를 이용한 암모니아 제거 및 순환여과식 양식장 적용
- Alternative Title
- Study on the removal of ammonia by switching polar electrochemical reactor and its application in recirculation of aquacultural water
- Abstract
- The recirculating aquaculture is a closed system that reuses aquaculture wastewater. This system has merits of spending minimum seawater and little change in temperature by external factors. However, it has problems of waste material accumulation in fishtank and rapid rise in the ammonia level. Now a days, electrolysis is being applied in the recirculating aquaculture system which is similar to chlorination by hypochlorite.
In this study, electrolysis with switching poles were explored to study the characteristic of removal efficiency of ammonia and the phenomenon of polarization by precipitates. First, current, which is the most important factor for product of free chlorine, was lower at the same potential in the electrolysis. By reason of decreasing current, yield of free chlorine is declined. Therefore, it should be prevented fouling phenomenon by switching poles. The period of switching poles equal to 60 second was optimum for high formation efficiency of free chlorine and low fouling phenomenon.
In the electrolysis of wastewater, the operating parameters of the electrochemical reactor were the current density and the number of cycles. The removal efficiency of ammonia and the generation of free chlorine were increased by rising the current density and the number of cycles.
For 240 hours in the pilot-scale aquaculture system, the concentration of ammonia in the reservoir tank should be kept below at 0.2 mg/L. For 8 cycles a day and 80 A of cell current, it can be kept at 0.2 mg/L.
- Author(s)
- 강기문
- Issued Date
- 2008
- Awarded Date
- 2008. 2
- Type
- Dissertation
- Keyword
- 극전환 암모니아 제거 전해반응
- Publisher
- 부경대학교 대학원
- URI
- https://repository.pknu.ac.kr:8443/handle/2021.oak/4073
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001984227
- Alternative Author(s)
- Kang, Ki Moon
- Affiliation
- 부경대학교 대학원
- Department
- 대학원 화학공학과
- Advisor
- 임준혁
- Table Of Contents
- List of Tables = ⅲ
List of Figures = ⅳ
Abstract = ⅶ
제1장 서론 = 1
제2장 문헌연구 = 4
2.1 암모니아 = 4
2.2 전해반응에 의한 암모니아 제거 특성 = 7
2.2.1 염소 파과점 = 9
2.2.2 모노클로라민 반응 = 10
2.2.3 디클로라민 반응 = 13
2.2.4 트리클라민 반응 = 13
제3장 실험장치 및 방법 = 15
3.1 실험장치 = 15
3.1.1 암모니아 제거를 위한 전해 시스템 = 15
3.1.2 Pilot-scale 시스템 = 17
3.2 실험방법 = 19
3.2.1 극전환 장치를 이용한 전해반응에서의 fouling 현상 확인 = 19
3.2.2 전해시스템 운전 및 시료 분석 = 20
3.2.3 Pilot-scale 사육시스템 운전 = 21
제4장 결과 및 고찰 = 22
4.1 극전환 전해반응기에서의 fouling 특성 = 22
4.1.1 극전환 주기에 따른 전류밀도 변화 및 유리염소 생성 효율 = 22
4.1.2 극전환에 따른 침전물의 생성 특성 = 27
4.2 암모니아 제거 특성 = 31
4.2.1 전류밀도에 따른 암모니아 제거 특성 = 31
4.2.2 순환비에 따른 암모니아 제거 특성 = 36
4.2.3 초기 암모니아 농도에 따른 암모니아 제거 특성 = 40
4.3. Pilot-scale 전해반응기 성능 = 42
4.3.1 전류 및 유량에 따른 유리염소 생성 농도 및 효율 = 42
4.3.2 순환비에 따른 수조내 수질 측정 = 45
4.3.2.1 암모니아 제거 특성 = 45
4.3.2.2 수조 내의 부유물질 제거 특성 = 45
4.3.2.3 비이온성암모니아의 농도 변화 = 48
4.4.2.4 수조 내 질산성 질소 제거 특성 = 48
제5장 결론 = 51
참고문헌 = 53
감사의 글 = 57
- Degree
- Master
-
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