합성피혁용 수분산 폴리우레탄의 물성과 응용
- Abstract
- Application and Properties of Water Based
Polyurethane for Synthetic Leather *
By
Seung-Yeol Lee
Department of Industrial Chemistry
Graduate School of Industry
Pukyung National University
Abstract
Waterborne resins can be classified as polymers with ionic stabilization (self-emulsifying binders)or external emulsifiers. The "core-shell" emulsions of the self-emulsifying polymer generation give excellent results in the industrial coating field. The methods of synthesis are polycondensation, polyaddition, polymerization or combinations of themselves. By these method resins with very low VOC-values are obtained. These resins can be alkyds, acrylics, epoxies, polyurethanes or combinations
of themselves. they are used as binders in top coats and primers (air-drying or stoving) for metal, plastics or wood in different industrial areas.
Polyurethane dispersions ( PUD) show very good properties in coatings for plastic materials, even by
low temperatures as -25°C (-13°F) as required in the car industry. 2-Component epoxy-polyamine sytems give outstanding results on metal, concrete and plastics. The main technological and ecological advantages are remarkable chemical and mechanical characteristics, field-proven application properties, noninflammability, interesting recycling possibilities and biodegradability.
- Author(s)
- 이승열
- Issued Date
- 2011
- Awarded Date
- 2011. 2
- Type
- Dissertation
- Publisher
- 부경대학교
- URI
- https://repository.pknu.ac.kr:8443/handle/2021.oak/9896
http://pknu.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001964158
- Department
- 산업대학원 공업화학학과
- Advisor
- 오대희
- Table Of Contents
- I 서론 1
II 이론적 배경 3
III 실 험 20
1. 시 약 20
2. 수 분산 PU의 제조 22
2.1 수 분산 PU의 합성 22
2.2 코팅용 수 분산PU의 합성 22
2.3 우레탄 반응도 26
2.4 물성 실험 26
2.4.1 [NCO]/[OH] 비율에 따른 물성 26
2.4.2 Carbodiimide 경화제 함량에 따른 Film의 신장율과 항복점 측정 26
2.4.3 NCO 경화제 함량 및 온도 변화에 따른 pot life변화 26
2.4.4 Tackiness 26
2.4.5 필름의 부착성 30
2.4.6 수지內 물과 에탄올의 증발 속도 33
2.4.7 수 분산 PU와 발포제에 의한 발포 효과 34
IV 결과 및 고찰 36
1. 수 분산 PU의 합성 36
2. [NCO]/[OH] 비율에 따른 물성 40
3. Carbodiimide 함량에 따른 코팅제의 영향 42
4. NCO 경화제 함량 및 온도변화에 따른 pot life변화 44
5. Tackiness 46
6. 필름의 부착성 47
7. 수지內 물과 에탄올의 증발 속도 48
8. 수 분산 PU와 발포제에 의한 발포 효과 51
V 결론 58
참고문헌 59
- Degree
- Master
-
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